Organic Reactions in Liquid Ammonia. IV
نویسندگان
چکیده
منابع مشابه
Kinetics and Mechanisms of Organic Reactions in Liquid Ammonia
The University Repository is a digital collection of the research output of the University, available on Open Access. Copyright and Moral Rights for the items on this site are retained by the individual author and/or other copyright owners. Users may access full items free of charge; copies of full text items generally can be reproduced, displayed or performed and given to third parties in any ...
متن کاملElectrochemical Reactions of Organic Compounds in Liquid Ammonia Part Iv. Reduction of Cyclooctatetraene
The electroreduction of COT in liquid ammonia at -38° and -65°C was investigated by cyclic voltammetric and controlled potential coulometric techniques. The results are interpreted by a two-step two-electron transfer reaction with strong ion-pairing of the COT dianion. Values for the heterogeneous electron transfer rate constants and the equilibrium constant of the disproportionation of the rad...
متن کاملElectrochemical reactions of organic compounds in liquid ammonia. III. Reductive alkylation of quinoline
The electrochemical behavior of quinoline in anhydrous liquid ammonia was investigated by cyclic voltammetry and controlled potential coulometry. In the absence of added alkylating agent, quinoline is reduced in two steps to yield the radical anion and dianion both of which undergo further chemical reaction. The radical anion species dimerizes to form the dimeric dianion which is stable in the ...
متن کاملElectrochemical reactions of organic compounds in liquid ammonia. I. Reduction of benzophenone
The electroreduction of benzophenone in liquid ammonia was studied by cyclic voltammetry. In anhydrous solutions, the reduction occurs in two reversible one-electron steps producing the anion radical and the dianion. In the presence of alcohol, the first reduction is unaffected and the second reduction wave becomes irreversible and is shifted toward positive potentials, following qualitatively ...
متن کاملElectrochemical reactions of organic compounds in liquid ammonia. II. Nitrobenzene and nitrosobenzene
The electrochemical behavior of nitrobenzene and nitrosobenzene in anhydrous liquid ammonia was investigated by cyclic voltammetry and controlled potential coulometry. In the absence of added protonating agents, nitrosobenzene and nitrobenzene are both reversibly reduced in two one-electron transfer steps to yield the stable radical anion and stable dianion species. In the presence of the weak ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: YAKUGAKU ZASSHI
سال: 1956
ISSN: 0031-6903,1347-5231
DOI: 10.1248/yakushi1947.76.8_897